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Chlorophyll is a chlorin pigment, which is structurally similar to and produced through the same metabolic pathway as other porphyrin pigments such as heme. At the center of the chlorin ring is a magnesium ion. For the structures depicted in this article, some of the ligands attached to the Mg2+ center are omitted for clarity. The chlorin ring can have several different side chains, usually including a long phytol chain. There are a few different forms that occur naturally, but the most widely distributed form in terrestrial plants is chlorophyll a. The general structure of chlorophyll a was elucidated by Hans Fischer in 1940, and by 1960, when most of the stereochemistry of chlorophyll a was known, Robert Burns Woodward published a total synthesis of the molecule as then known. In 1967, the last remaining stereochemical elucidation was completed by Ian Fleming, and in 1990 Woodward and co-authors published an updated synthesis.
(For detailed information on various structures and associated images, visit http://en.wikipedia.org/wiki/Chlorophyll)
4Write the unbalanced equation. Chemical formulas of reactants are listed on the lefthand side of the equation. Products are listed on the righthand side of the equation. Reactants and products are separated by putting an arrow between them to show the direction of the reaction. Reactions at equilibrium will have arrows facing both directions. Balance the equation. Apply the Law of Conservation of Mass to get the same number of atoms of every element on each side of the equation. Tip: Start by balancing an element that appears in only one reactant and product. Once one element is balanced, proceed to balance another, and another, until all elements are balanced. Balance chemical formulas by placing coefficients in front of them. Do not add subscripts, because this will change the formulas. Indicate the states of matter of the reactants and products. Use (g) for gaseous substances. Use (s) for solids. Use (l) for liquids. Use (aq) for species in solution in water. Write the state of matter immediately following the formula of the substance it describes. Worked Example Problem
Tin oxide is heated with hydrogen gas to form tin metal and water vapor. Write the balanced equation that describes this reaction.
Write the unbalanced equation. SnO2 + H2 → Sn + H2O
Refer to Table of Common Polyatomic Ions and Formulas of Ionic Compounds if you have trouble writing the chemical formulas of the products and reactants.
Balance the equation. Look at the equation and see which elements are not balanced. In this case, there are two oxygen atoms on the lefthand side of the equation and only one on the righthand side. Correct this by putting a coefficient of 2 in front of water:
SnO2 + H2 → Sn + 2 H2O
This puts the hydrogen atoms out of balance. Now there are two hydrogen atoms on the left and four hydrogen atoms on the right. To get four hydrogen atoms on the right, add a coefficient of 2 for the hydrogen gas. Remember, coefficients are multipliers, so if we write 2 H2O it denotes 2x2=4 hydrogen atoms and 2x1=2 oxygen atoms.
SnO2 + 2 H2 → Sn + 2 H2O
The equation is now balanced. Be sure to double-check your math! Each side of the equation has 1 atom of Sn, 2 atoms of O, and 4 atoms of H.
Indicate the physical states of the reactants and products. To do this, you need to be familiar with the properties of various compounds or you need to be told what the phases are for the chemicals in the reaction. Oxides are solids, hydrogen forms a diatomic gas, tin is a solid, and the term 'water vapor' indicates that water is in the gas phase:
SnO2(s) + 2 H2(g) → Sn(s) + 2 H2O(g)
(http://chemistry.about.com/cs/stoichiometry/a/aa042903a.htm)
4Earth's atmosphere can be divided into five main layers. These layers are mainly determined by whether temperature increases or decreases with altitude. From highest to lowest, these layers are:
The outermost layer of Earth's atmosphere extends from the exobase upward. Here the particles are so far apart that they can travel hundreds of kilometres without colliding with one another. Since the particles rarely collide, the atmosphere no longer behaves like a fluid. These free-moving particles follow ballistic trajectories and may migrate into and out of the magnetosphere or the solar wind. The exosphere is mainly composed of hydrogen and helium.
Temperature increases with height in the thermosphere from the mesopause up to the thermopause, then is constant with height. The temperature of this layer can rise to 1,500 °C (2,730 °F), though the gas molecules are so far apart that temperature in the usual sense is not well defined. The International Space Station orbits in this layer, between 320 and 380 km (200 and 240 mi). The top of the thermosphere is the bottom of the exosphere, called the exobase. Its height varies with solar activity and ranges from about 350–800 km (220–500 mi; 1,100,000–2,600,000 ft).
The mesosphere extends from the stratopause to 80–85 km (50–53 mi; 260,000–280,000 ft). It is the layer where most meteors burn up upon entering the atmosphere. Temperature decreases with height in the mesosphere. The mesopause, the temperature minimum that marks the top of the mesosphere, is the coldest place on Earth and has an average temperature around −85 °C (−121.0 °F; 188.1 K)[3]. Due to the cold temperature of the mesophere, water vapor is frozen, forming ice clouds (or Noctilucent clouds). A type of lightning referred to as either sprites or ELVES, form many miles above thunderclouds in the trophosphere.
The stratosphere extends from the tropopause to about 51 km (32 mi; 170,000 ft). Temperature increases with height, which restricts turbulence and mixing. The stratopause, which is the boundary between the stratosphere and mesosphere, typically is at 50 to 55 km (31 to 34 mi; 160,000 to 180,000 ft). The pressure here is 1/1000th sea level.
The troposphere begins at the surface and extends to between 7 km (23,000 ft) at the poles and 17 km (56,000 ft) at the equator, with some variation due to weather. The troposphere is mostly heated by transfer of energy from the surface, so on average the lowest part of the troposphere is warmest and temperature decreases with altitude. This promotes vertical mixing (hence the origin of its name in the Greek word "τροπή", trope, meaning turn or overturn). The troposphere contains roughly 80%[citation needed] of the mass of the atmosphere. The tropopause is the boundary between the troposphere and stratosphere. Other layers
Within the five principal layers determined by temperature are several layers determined by other properties.
The ozone layer is contained within the stratosphere. In this layer ozone concentrations are about 2 to 8 parts per million, which is much higher than in the lower atmosphere but still very small compared to the main components of the atmosphere. It is mainly located in the lower portion of the stratosphere from about 15–35 km (9.3–22 mi; 49,000–110,000 ft), though the thickness varies seasonally and geographically. About 90% of the ozone in our atmosphere is contained in the stratosphere. The ionosphere, the part of the atmosphere that is ionized by solar radiation, stretches from 50 to 1,000 km (31 to 620 mi; 160,000 to 3,300,000 ft) and typically overlaps both the exosphere and the thermosphere. It forms the inner edge of the magnetosphere. It has practical importance because it influences, for example, radio propagation on the Earth. It is responsible for auroras.
The homosphere and heterosphere are defined by whether the atmospheric gases are well mixed. In the homosphere the chemical composition of the atmosphere does not depend on molecular weight because the gases are mixed by turbulence.[4] The homosphere includes the troposphere, stratosphere, and mesosphere. Above the turbopause at about 100 km (62 mi; 330,000 ft) (essentially corresponding to the mesopause), the composition varies with altitude. This is because the distance that particles can move without colliding with one another is large compared with the size of motions that cause mixing. This allows the gases to stratify by molecular weight, with the heavier ones such as oxygen and nitrogen present only near the bottom of the heterosphere. The upper part of the heterosphere is composed almost completely of hydrogen, the lightest element.
The planetary boundary layer is the part of the troposphere that is nearest the Earth's surface and is directly affected by it, mainly through turbulent diffusion. During the day the planetary boundary layer usually is well-mixed, while at night it becomes stably stratified with weak or intermittent mixing. The depth of the planetary boundary layer ranges from as little as about 100 m on clear, calm nights to 3000 m or more during the afternoon in dry regions.
The average temperature of the atmosphere at the surface of Earth is 14 °C (57 °F; 287 K)[5] or 15 °C (59 °F; 288 K)[6], depending on the reference.[7] [8][9]
http://en.wikipedia.org/wiki/Atmosphere_of_Earth
3Mutarotation is the change in the optical rotation that occurs by epimerization (that is the change in the equilibrium between two epimers, when the corresponding stereocenters interconvert). Cyclic sugars show mutarotation as α and β anomeric forms are interconvert.[1] The optical rotation of the solution depends on the optical rotation of each anomer and their ratio in the solution.
Please refer to http://en.wikipedia.org/wiki/Mutarotation for more information.
3Art refers to the way of doing specific things; it indicates how an object can be achieved. In the words of George R. Terry, "Art is bringing about of a desired result through the application of skill." Art is, thus, skilful application of knowledge which entirely depends on the inherent capacity of a person which comes from within a person and is learned from practice and experience. In this sense, management is certainly an art as a manager uses his skill, knowledge and experience in solving various problems, both complicated and non-complicated that arise in the working of his enterprise successful. In the words of Ernest Dale, "Management is considered as an art rather than science mainly because managerial skill is a personnel possession and is intuitive."
See http://www.rajputbrotherhood.com/knowledge-hub/business-studies/management-is-an-art-as-well-as-science.html for more information.
3Kepler's laws are:
1) The orbit of every planet is an ellipse with the Sun at a focus.
2) A line joining a planet and the Sun sweeps out equal areas during equal intervals of time.
3) The square of the orbital period of a planet is directly proportional to the cube of the semi-major axis of its orbit.
3A stoma is a pore, found in the leaf and stem epidermis that is used for gas exchange. The pore is bordered by a pair of specialized parenchyma cells known as guard cells which are responsible for regulating the size of the opening. The term stoma is also used collectively to refer to an entire stomatal complex, both the pore itself and its accompanying guard cells. Air containing carbon dioxide and oxygen enters the plant through these openings where it is used in photosynthesis and respiration, respectively. Oxygen produced by photosynthesis in the spongy layer cells (parenchyma cells with pectin) of the leaf interior exits through these same openings. Also, water vapor is released into the atmosphere through these pores in a process called transpiration.
Refer to http://en.wikipedia.org/wiki/Stoma for more information.
3A stereotype is a popular belief about specific social groups or types of individuals. The concepts of "stereotype" and "prejudice" are often confused with many other different meanings. Stereotypes are standardized and simplified conceptions of groups based on some prior assumptions.
Source: http://en.wikipedia.org/wiki/Stereotype
2Radiation is energy that comes from a source and travels through space and may be able to penetrate various materials. Light, radio, and microwaves are types of radiation that are called nonionizing. The kind of radiation discussed in this document is called ionizing radiation because it can produce charged particles (ions) in matter.
Ionizing radiation is produced by unstable atoms. Unstable atoms differ from stable atoms because unstable atoms have an excess of energy or mass or both. Radiation can also be produced by high-voltage devices (e.g., x-ray machines).
Atoms with unstable nuclei are said to be radioactive. In order to reach stability, these atoms give off, or emit, the excess energy or mass. These emissions are called radiation. The kinds of radiation are electromagnetic (like light) and particulate (i.e., mass given off with the energy of motion). Gamma radiation and x rays are examples of electromagnetic radiation. Gamma radiation originates in the nucleus while x rays come from the electronic part of the atom. Beta and alpha radiation are examples of particulate radiation.
Interestingly, there is a "background" of natural radiation everywhere in our environment. It comes from space (i.e., cosmic rays) and from naturally occurring radioactive materials contained in the earth and in living things.
http://hps.org/publicinformation/ate/faqs/whatisradiation.html
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