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Descriptive Inorganic Chemistry
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1. Where it all comes from
1.1 The Structure of the earth
1.2 Composition of Earth's Crust
1.3 Rocks and Minerals
1.4 Weathering
1.5 Obtaining Metals
1.6 Some Metals Today
1.7 Non Metallic Inorganic Minerals
References for further Reading
Problems
Chapter 2 Atomic and Molecular Structure
2.1 Atomic Structure
2.1.1 Quantum Numbers
2.1.2 Hydrogen Like Orbitals
2.2 Properties of Atoms
2.2.1 Electron Configurations
2.2.2 Ionization Energy
2.2.3 Electron Affinity
2.2.4 Electronegativity
2.3 Molecular Structure
2.3.1 Molecular Orbitals
2.3.2 Orbital Overlap
2.3.3 Polar Molecules
2.3.4 Geometry of Molecules Having Single Bonds
2.3.5 Valence shell Electron Pair Repulsion(VSEPR)
2.4 Symmetry
2.5 Resonance
References for further Reading
Problems
Chapter 3 Ionic Bonding, Crystals and Intermolecular Forces
3.1 Ionic Bonds
3.1.1 Energetics of the Ionic Bond
3.1.2 Radius Ration Effects
3.1.3 Crystal Structures
3.2 Intermolecular Interactions
3.2.1 Dipole Dipole Forces
3.2.2 Dipole induced Dipole Forces
3.2.3 London Dispersion Forces
3.2.4 Hydrogen Bonding
3.2.5 Solubility Parameters
References for Further Reading
Problems
Chapter 4 Reactions and Energy Relationship
4.1 Thermodynamic Considerations
4.1.1 The Boltzmann Distribution Law
4.1.2 Reactions and ΔG and T
4.1.3 Relationship between
4.1.4 Bond Enthalpies
4.2 Combination Reactions
4.3 Decomposition Reactions
4.4 Redox Reactions
4.5 Hydrolysis Reactions
4.6 Replacement Reactions
4.7 Metathesis
4.8 Neutralization Reactions
References for Further Reading
Problems
5. Acids, Bases and NonAqueous Solvents
5.1 Acid- Base Chemistry
5.1.1 Factors Affecting Acid Strength
5.1.2 Factors Affecting Base Strength
5.1.3 Molten salt Protonic Acids
5.1.4 Lewis Theory
5.1.5 Hard soft Acid-Base Principle (HSAB)
5.1.6 Applications of the Hard Soft Interaction Principle (HSIP)
5.2 Nonaqueous Solvents
5.2.1 The Solvent Concept
5.2.2 The Coordination Model
5.2.3 Liquid Ammonia
5.2.4 Reactions in Liquid Ammonia
5.2.5 Liquid Hydrogen Fluoride
5.2.6 Liquid Sulphur Dioxide
5.3 Superacids
5.4 References for
6. Hydrogen
6.1 Elemental and Positive Hydrogen
6.2 Occurence and Properties
6.3 Hydrides
6.3.1 Ionic Hydrides
6.3.2 Interstiial Hydrides
6.3.3 Covalent Hydrides
References for Further Reading
Problems
7. The Group IA and IIA Metals
7.1 General Characteristics
7.2 Oxides and Hydroxides
7.3 Halides
7.4 Sulfides
7.5 Nitrides and Phosphides
7.6 Carbides, Cyanides, Cynamides and Amides
7.7 Carbonates, Nitrates, Sulfates and Phosphates
7.8 Organic Derivatives
References for Further Reading
Problems
8. Boron
8.1 Elemental Boron
8.2 Bonding in Boron Compounds
8.3 Boron Compounds
8.3.1 Borides
8.3.2 Boron Halides
8.3.3 Boron Hydrides
8.3.4 Boron Nitrides
8.3.5 Polyhedral Boranes
References for further reading
Problems
9. Aluminium, Galium, Indium and Thalium
9.1 The Elements
9.2 Oxides
9.3 Hydrides
9.4 Halides
9.5 Other Compounds
9.6 Organometallic Compounds
References for Further Reading
Problems
10. Carbon
10.1 The Element
10.2 Industrial Uses of Carbon
10.2.1 Advanced Composites
10.2.2 Manufactured Carbons
10.2.3 Chemical uses of Carbons
10.3 Carbon Compounds
10.3.1 Ionic Carbides
10.3.2 Covalent Carbides
10.3.3 Interestitial Carbides
10.3.4 Oxides of Carbon
10.3.5 Carbon Halides
10.3.6 Carbon Nitrides
10.3.7 Carbon Sulfides
References for Further Reading
Problems
11. Silicon, Germanium ,Tin and Lead
11.1 The Elements
11.2 Hydrides of the group IVA Elements
11.3 Oxides of the Group IVA Elements
11.3.1 The +2 Oxides
11.3.2 The +4 Oxides
11.3.3 Glass
11.4 Silicates
11.5 Zeolites
11.6 Halides of the group IVA Elements
11.6.1 The +2 Halides
11.6.2 The +4 Halides
11.7 Organic Compounds
11.8 Miscellaneous Compounds
References for further Reading
Problems
12. Nitrogen
12.1 Elemental Nitrogen
12.2 Nitrides
12.3 Ammonia and Aquo Compounds
12.4 Hydrogen Compounds
12.4.1 Ammonia
12.4.2 Hydrazine N2H4
12.4.3 Dimine N2H2
12.4.4 Hydrogen Azide HN3
12.5 Nitrogen Halides
12.5.1 NX3 Compounds
12.5.2 Difluorodiazine N2F2
12.5.3 Oxyhalides
12.6 Nitrogen Halides
12.6.1 Nitrous Oxide N2O
12.6.2 Nitric Oxide
12.6.3 Dinitrogen Trioxide, NO2 nad N2O4
12.6.4 Nitrogen Dioxide NO2 and N2O4
12.6.5 Dinitrogen Pentoxide, N2O5
12.7 Oxyacids
12.7.1 Hyponitrous Acid, H2N2O2
12.7.2 Nitrous Acid, HNO2
12.7.3 Nitric Acid HNO3
References for Further Reading
Problems
13. Phosphorous Arsenic, Antimon and Bismuth
13.1 Occurence
13.2 Preparation and Properties of the Elements
13.3 Hydrides
13.4 Oxides
13.4.1 The +3 Oxides
13.4.2 The +5 Oxides
13.5 Sulfides
13.6 Halides
13.6.1 Halides of the Type E2X4
13.6.2 Trihalides
13.6.3 Pentahalides and Oxyhalides
13.7 Phosphonitrilic Compounds
13.8 Acids and their salts
13.8.1 Phosphorous Acid and Phosphites
13.8.2 Phosphoric Acid and Phosphates
13.9 Fertilizer Production
References for Further Reading
Problems
14. Oxygen
14.1 Elemental Oxygen O2
14.2 Ozone.O3
14.3 Preparation of Oxygen
14.4 Binary Compounds of Oxygen
14.4.1 Ionic Oxides
14.4.2 Covalent Oxides
14.4.3 Amphoteric Oxides
14.4.4 Peroxides and Superoxides
14.5 Positive Oxygen
References for Further Reading
Problems
15. Sulfur, Selenium and Tellurium
15.1 Occurence of Sulphur
15.2 Occurence of Selenium and Tellurium
15.3 Elemental Sulfur
15.4 Elemental Selenium and Tellurim
15.5 Reactions of Elemental Selenium and Tellurium
15.6 Hydrogen Compounds
15.7 Oxides of Sulphur, Selenium ad Tellurium
15.7.1 Dioxides
15.7.2 Trioxides
15.8 Halogen Compounds
15.9 Nitrogen Compounds
15.10 Oxyhalides of Sulfur and Selenium
15.10.1 Oxidation State +4
15.10.2 Oxidation State +6
15.11 Oxyacids of Sulfur, Selenium and Tellurium
15.11.1 Sulfurous Acid and Sulfites
15.11.2 Dithinous Acid and Dithionites
15.11.3 Dithionic Acid and Dithionates
15..1.4 Peroxydisulfuric Acid and Peroxydisulfates
15.1.5 Oxyacids of Selenium and Tellurium
15.12 Sulfuric Acid
15.12.1 Preparation of Sulphuric Acid
15.12.2 Physical Properties of Sulfuric Acid
15.12.3 Chemical Properties of Sulfuric Acid
15.12.4 Uses of Sulphuric Acid
References for Further Reading
Problems
16. Halogens
16.1 Occurence
16.2 The Elements
16.3 Interhalogens
16.3.1 Type XX
16.3.2 Type XX3
16.3.3 Type XX5
16.3.4 Type XX7
16.3.5 Structures
16.3.6 Chemical Properties
16.4 Polyatomic Cations and Anions
16.4.1 Polyatomic Halogen Cations
16.4.2 Interhalogen Cations
16.4.3 Polyatomic Halogen Anions
16.5 Hydrogen Halides
16.5.1 Physical Properties
16.5.2 Preparation
16.6 Oxides
16.6.1 Oxygen Fluorides
16.6.2 Chlorine Oxides
16.6.3 Bromine Oxides
16.6.4 Iodine Oxides
16.6.5 Oxyfluorides of the heavier Halogens
16.7 Oxyacids and Oxyanions
16.7.1 Hypohalous Acids and Hypohalites
16.7.2 Halous acids and Halites
16.7.3 Halic acids and Halates
16.7.4 Perhalic Acids and Parhalates
References for Further Reading
Problems
17. Noble Gases
17.1 The Elements
17.2 The Xenon Fluorides
17.3 Reactions of Xenon Fluorides
17.4 Oxyfluorides and Oxides
17.5 References for Further Reading
17.6 Problems
18. The transition Elements
18.1 The Metals
18.1.1 Structures of Metals
18.1.2 Alloys
18.2 Oxides
18.3 Halides and Oxyhalides
18.4 Miscellaneous Compounds
18.5 The Lanthanides
References for Further Reading
Problems
19. Structure and Bonding in Coordination Compounds
19.1 Types of Ligands and Complexes
19.2 Naming Coordination Compounds
19.3 Isomerism
19.3.1 Gemetrical Isomerism
19.3.2 Optical Isomerism
19.3.3 Linkage Isomerism
19.3.4 Ionization Isomerism
19.3.5 Coordination Isomerism
19.3.6 Polymerisation Isomerism
19.3.7 Hydrate Isomerism
19.4 Factors affecting the stability of Complexes
19.4.1 The nature of the Acids base Interaction
19.4.2 The chelate Effect
19.4.3 Ring Size and Structure
19.5 A Valence bond Approach to bonding in complexes
19.6 Back Donation
19.7 Ligand Field Theory
19.7.1 Octahedral Fields
19.7.2 Tetrahedral, Tetragonal and Square planar fields
19.7.3 Ligand Field Stabilization Energy
19.7.4 Ligand Field Stabilization Energy
19.8 Jahn Teller Distribution
References for further reading
Problems
20. Synthesis and Reactions of Coordination Compounds
20.1 Synthesis of Coordination Compounds
20.1.1 Reaction of a metal salt with a legand
20.1.2 Ligand replacement Reactions
20.1.3 Reaction of two metal Compounds
20.1.4 Oxidation Reduction Reactions
20.1.5 Partial Decomposition
20.1.6 Size and solubility Relationships
20.1.7 Reactions of metal salts with amine Salts
20.2 A Survey of Reactions Types
20.2.1 Ligand Substitution
20.2.3 Oxidative Addition (Oxad) Reactions
20.2.4 Insertion Reactions
20.2.5 Electron Transfer Reactions
20.3 A Closer look at substitution reactions
20.4 Substitution in square planar complexes
20.4.1 Mechanisms
20.4.2 The Trans Effect
20.4.3 Causes of the Trans Effect
20.5 Substitution in Octahedral Complexes
20.5.1 Classification based on rates
20.5.2 The Effect of LFSE on Rate of Substitution
20.5.3 The Sn 1 CB Mechanism
References for Further Reading
Problems
21. Organometallic Compounds
21.1 Structure and Bonding in Metal Alkyls
21.2 Preparation of Organometallic Compounds
21.3 Reactions of Metal Alkyls
21.4 Cyclopentadienyl Complexes ( Metallocenes)
21.5 Metal Carbonyl Complexes
21.5.1 Binary metal Carbonyls
21.5.2 Structures of metal Carbonyls
21.5.3 Preparation of Metal Carbonyls
21.5.4 Reactions of Carbonyls
21.6 Metal Olefin Complexes
21.6.1 Structure and Bonding
21.6.2 Preparation of metal olefin Complexes
21.7 Complexes of Benzene and Related Aromatics
References for Further Reading
Problems
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